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Kinetics of the addition of propene to cyclohexa‐1,3‐diene in the gas phase

par Debande, G.;Huybrechts, Guy
Référence International journal of chemical kinetics, 6, 4, page (545-552)
Publication Publié, 1974

Article révisé par les pairs

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Résumé :

The addition of propene to cyclohexa‐1,3‐diene has been studied between 512 and 638°K at pressures between 70 and 640 torr. The products are endo‐ and exo‐5‐methylbicyclo [2.2.2] oct‐2‐ene, and their formations are second order. The rate constants (in 1./mole‐sec) are given by (Formula Presented.) (Formula Presented.) The results are discussed in terms of a biradical mechanism. Copyright © 1974 John Wiley & Sons, Inc.