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Transport properties of the binary mixtures of the three organic liquids toluene, methanol, and cyclohexane

par Lapeira, Estela;Gebhardt, M.;Triller, Thomas;Mialdun, Aliaksndr ;Kohler, Werner;Shevtsova, Valentina ;Bou-Ali, Mounir Mounir
Référence The Journal of Chemical Physics, 146, 9, 094507
Publication Publié, 2017-03

Article révisé par les pairs

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Résumé :

We report on the measurements of diffusion (D), thermodiffusion (DT), and Soret (ST) coefficients in binary pairs of the ternary system toluene-methanol-cyclohexane using different instrumental techniques: microgravity measurements (SODI/DCMIX2) on the International Space Station, thermogravitational column in combination with sliding symmetric tubes, optical beam deflection, optical digital interferometry, and counter flow cell. The binary systems have large regions where the mixtures are either not miscible or the Soret coefficient is negative. All the coefficients have been measured over a wide composition range with the exception of a miscibility gap. Results from different instruments and literature data are in favorable agreement over a broad composition range. Additionally, we have carefully measured the physical properties and the optical contrast factors (∂n/∂c)p,T and (∂n/∂T)p,c. The latter ones were also calculated using the Looyenga equation. The measurements in methanol-cyclohexane mixture revealed a decay of the diffusion coefficient when approaching the miscibility gap. We have interpreted this in the spirit of the pseudospinodal concept.