par Chiurdoglu, Grégoire ;Proost, De R.D.;Tursch, Bernard
Référence Bulletin des Sociétés chimiques belges, 67, 5-6, page (198-203)
Publication Publié, 1958
Article révisé par les pairs
Résumé : Infrared spectra of homologous series of cyclanols, chlorocyclanes and bromocyclanes have been recorded. They show, in each series, a splitting of the δch2 band near 1450 cm−1, except in the case of cyclohexane derivatives. The magnitude of this splitting varies with the thermodynamic strain of the ring. This phenomenon is attributed to an intramolecular interaction between the methylene groups. Copyright © 1958 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim