par Joly, Marc;Defay, Nicole ;Martin, Richard ;Declerq, Jean Paul;Germain, Gabriel;Soubrier‐Payen, Bernadette;Van Meerssche, Maurice
Référence Helvetica chimica acta, 60, 2, page (537-560)
Publication Publié, 1977
Référence Helvetica chimica acta, 60, 2, page (537-560)
Publication Publié, 1977
Article révisé par les pairs
Résumé : | Bridged helicenes: 3,15‐ethano‐ and 3,15‐(2‐oxapropano)‐[7]helicene The title compounds (35 and 33, see Scheme 4) have been synthesized from a common intermediate: 3,15‐dimethoxycarbonyl‐[7]helicene (26). The conformation of the bridged [7]helicenes (X‐ray diffraction) and their 1H‐NMR. spectra have been compared to the conformation and 1H‐NMR. spectra of [7]helicene and 3,15‐dimethyl‐[7]helicene (10). Copyright © 1977 Verlag GmbH & Co. KGaA, Weinheim |