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Collision-induced absorption in the v2 fundamental band of CH4. I. Determination of the quadrupole transition moment

par Tipping, Richard R.H.;Brown, Alex;Ma, Qiancheng;Hartmann, Jean Michel;Boulet, Christian;Liévin, Jacques
Référence The Journal of Chemical Physics, 115, 19, page (8852-8857)
Publication Publié, 2001-11

Article révisé par les pairs

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Résumé :

The vibrating quadrupole of CH4 interacting with the polarizability of the perturber is proposed as another collision-induced dipole mechanism. This mechanism would be present for absorption in the v2 region. For demonstration purposes, the simplest case of CH4-Ar is considered.