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The origin of some irreproducibilities in the kinetic study of the reaction W(CO)5 (aniline) + P(C6H5)3

par Nasielski, Jacques ;Vermeulen, Martine ;Leempoel, Patrick
Référence Journal of organometallic chemistry, 102, 2, page (195-198)
Publication Publié, 1975-12

Article révisé par les pairs

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Résumé :

The title reaction has been examined under strict exclusion of light and air, but the rate was still found to be irreproducible. The variability can be ascribed in part to the unavoidable presence of traces of triphenylphosphine oxide in triphenylphosphine. © 1975.