par Didier, Delphine ;Sergueev, Serguei
Référence Tetrahedron, 63, 18, page (3864-3869)
Publication Publié, 2007-04
Référence Tetrahedron, 63, 18, page (3864-3869)
Publication Publié, 2007-04
Article révisé par les pairs
Résumé : | In this paper, we report the synthesis of amino and aminomethyl derivatives of Tröger's base (±)-1 and (±)-2. The key steps in the synthesis of (±)-1 and (±)-2 are Pd-catalyzed amination and cyanation, respectively, of the easily accessible dihalo derivatives (±)-3. These compounds are important intermediates in the synthesis of new ligands and building blocks for H-bonded supramolecular architectures. © 2007 Elsevier Ltd. All rights reserved. |