par Troian Gautier, Ludovic ;Moucheron, Cécile
Référence Molecules (Print Archive Edition), 19, 4, page (5028-5087)
Publication Publié, 2014
Article révisé par les pairs
Résumé : In this review, we first discuss the photophysics reported in the literature for mononuclear ruthenium complexes bearing ligands with extended aromaticity such as dipyrido[3,2-a:2',3'-c]phenazine (DPPZ), tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]- phenazine (TPPHZ), tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]acridine (TPAC), 1,10- phenanthrolino[5,6-b]1,4,5,8,9,12-hexaazatriphenylene (PHEHAT) 9,11,20,22-tetraazatetrapyrido[ 3,2-a:2',3'-c:3'',2''-l:2''',3'''-n]pentacene (TATPP), etc. Photophysical properties of binuclear and polynuclear complexes based on these extended ligands are then reported. We finally develop the use of binuclear complexes with extended p-systems for applications such as photocatalysis. © 2014 by the authors; licensee MDPI, Basel, Switzerland.