par Brocas, Jean
Référence Journal of statistical physics, 24, 1, page (199-214)
Publication Publié, 1981-01
Article révisé par les pairs
Résumé : We review some aspects of dynamic stereochemistry related to the classification theory of rearrangement mechanisms. This classification is based on the symmetry of the molecular skeleton and has been widely used in connection with nuclear magnetic resonance line shape analysis. It is also related to the Longuet-Higgins approach to nonrigidity and may be used to predict the consequences of various tunneling mechanisms in rotation or vibration spectroscopy. © 1981 Plenum Publishing Corporation.