par Figeys, Hubert 
;Nasielski, Jacques
Référence Spectrochimica Acta Part A: Molecular Spectroscopy, 23, 3, page (465-470)
Publication Publié, 1967-03
;Nasielski, Jacques Référence Spectrochimica Acta Part A: Molecular Spectroscopy, 23, 3, page (465-470)
Publication Publié, 1967-03
Article révisé par les pairs
| Résumé : | The sensitivity to solvent effects of νCO vibrations in polycyclic aromatic aldehyde is characterized by the slope of the straight line obtained by plotting ΔνCO [νCO (hexane)-νCO (solvent)] vs. ΔνCO for 1-naphthaldehyde (cf. Fig. 1). This property can be linearly related either to the pKb of the molecules or to the π electronic charge (calculated by L.C.A.O.) on the oxygen atom of the CO group. The scope of this relation is critically discussed. © 1967. |
