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(3+1)-resonantly enhanced multiphoton ionization-photoelectron spectroscopy of the (3d-4s) supercomplex of acetylene: The geometry of the E state revisited through experiment and theory

par Blanchet, Valérie;Boyé, Séverine;Zamith, Sébastien;Campos, Andréa;Girard, Bertrand;Liévin, Jacques ;Gauyacq, Dolores
Référence The Journal of Chemical Physics, 119, 7, page (3751-3762)
Publication Publié, 2003-08

Article révisé par les pairs

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Résumé :

A study was performed on the (3 + 1)-resonantly enhanced multiphoton ionization-photoelectron spectroscopy of the (3d-4s) supercomplex of acetylene. The Renner-Teller coupling occurring in the ion ground state was considered during the photoelectron analysis. The results showed the tentative frequencies for the stretching mode as well as for the bending mode.